Array of conductive vias, methods of forming a memory array, and methods of forming conductive vias

ABSTRACT

A method of forming conductive vias comprises forming at least three parallel line constructions elevationally over a substrate. The line constructions individually comprise a dielectric top and dielectric sidewalls. A conductive line is formed elevationally over and angles relative to the line constructions. The conductive line comprises a longitudinally continuous portion and a plurality of conductive material extensions that individually extend elevationally inward between immediately adjacent of the line constructions. Etching is conducted elevationally through the longitudinally continuous portion and partially elevationally into the extensions at spaced locations along the conductive line to break-up the longitudinally continuous portion to form individual conductive vias extending elevationally between immediately adjacent of the line constructions. Methods of forming a memory array are also disclosed. Arrays of conductive vias independent of method of manufacture are also disclosed.

RELATED PATENT DATA

This patent resulted from a divisional application of U.S. patent application Ser. No. 14/307,121, filed Jun. 17, 2014, entitled “Array Of Conductive Vias, Methods Of Forming A Memory Array, And Methods Of Forming Conductive Vias”, naming Sanh D. Tang, Wolfgang Mueller, Brent Gilgen, Dylan Macmaster, and Jim A. Jozwiak as inventors, the disclosure of which is incorporated by reference.

TECHNICAL FIELD

Embodiments disclosed herein pertain to arrays of conductive vias, to methods of forming a memory array, and to methods of forming conductive vias.

BACKGROUND

A continuing goal in integrated circuitry fabrication is to make ever smaller and closer packed circuit components. As integrated circuitry density has increased, there is often greater reduction in the horizontal dimension of circuit components as compared to the vertical dimension. In many instances, the vertical dimension has increased. As size decreases and density increases, there is a continuing challenge to provide sufficient conductive contact area between electrically coupled circuit components particularly where that coupling is through contacting surfaces that are substantially horizontal. For example, elevationally elongated conductive vias formed in contact openings are commonly used for electrically coupling circuit components that are at different elevations relative to one another. As circuit components become smaller and closer together, it becomes increasingly difficult to control critical dimension, mask alignment, and provide acceptable margins of error when forming contact openings to lower elevation circuit components. In some instances after forming conductive vias, additional conductive material is deposited directly against the vias and is subsequently patterned to enlarge targeting area and/or provide greater conductivity for overlying devices that electrically couple to the vias.

Memory is one type of integrated circuitry commonly incorporating conductive vias. Integrated memory is usually fabricated in one or more arrays of individual memory cells. The memory cells might be volatile, semi-volatile, or nonvolatile. Nonvolatile memory cells can store data for extended periods of time in the absence of power. Nonvolatile memory is conventionally specified to be memory having a retention time of at least about 10 years. Volatile memory dissipates, and is therefore refreshed/rewritten to maintain data storage. Volatile memory may have a retention time of milliseconds, or less. The memory cells are configured to retain or store memory in at least two different selectable states. In a binary system, the states are considered as either a “0” or a “1”. In other systems, at least some individual memory cells may be configured to store more than two levels or states of information.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a diagrammatic top plan view of a substrate fragment in process accordance with an embodiment of the invention.

FIG. 2 is a diagrammatic sectional view taken through line 2-2 in FIG. 1.

FIG. 3 is a diagrammatic sectional view taken through line 3-3 in FIG. 1.

FIG. 4 is a diagrammatic sectional view taken through line 4-4 in FIG. 1.

FIG. 5 is a view of the FIG. 1 substrate at a processing step subsequent to that shown by FIG. 1.

FIG. 6 is a diagrammatic sectional view taken through line 6-6 in FIG. 5.

FIG. 7 is a diagrammatic sectional view taken through line 7-7 in FIG. 5.

FIG. 8 is a diagrammatic sectional view taken through line 8-8 in FIG. 5.

FIG. 9 is a view of the FIG. 5 substrate at a processing step subsequent to that shown by FIG. 5.

FIG. 10 is a diagrammatic sectional view taken through line 10-10 in FIG. 9.

FIG. 11 is a diagrammatic sectional view taken through line 11-11 in FIG. 9.

FIG. 12 is a diagrammatic sectional view taken through line 12-12 in FIG. 9.

FIG. 13 is a view of the FIG. 9 substrate at a processing step subsequent to that shown by FIG. 9.

FIG. 14 is a diagrammatic sectional view taken through line 14-14 in FIG. 13.

FIG. 15 is a diagrammatic sectional view taken through line 15-15 in FIG. 13.

FIG. 16 is a diagrammatic sectional view taken through line 16-16 in FIG. 13.

FIG. 17 is a view of the FIG. 13 substrate at a processing step subsequent to that shown by FIG. 13.

FIG. 18 is a diagrammatic sectional view taken through line 18-18 in FIG. 17.

FIG. 19 is a diagrammatic sectional view taken through line 19-19 in FIG. 17.

FIG. 20 is a diagrammatic sectional view taken through line 20-20 in FIG. 17.

FIG. 21 is a view of the FIG. 17 substrate at a processing step subsequent to that shown by FIG. 17.

FIG. 22 is a diagrammatic sectional view taken through line 22-22 in FIG. 21.

FIG. 23 is a diagrammatic sectional view taken through line 23-23 in FIG. 21.

FIG. 24 is a diagrammatic sectional view taken through line 24-24 in FIG. 21.

FIG. 25 is a view of the FIG. 21 substrate at a processing step subsequent to that shown by FIG. 21.

FIG. 26 is a diagrammatic hybrid schematic and structural sectional view taken through line 26-26 in FIG. 25.

FIG. 27 is a diagrammatic hybrid schematic and structural sectional view taken through line 27-27 in FIG. 25.

FIG. 28 is a diagrammatic sectional view taken through line 28-28 in FIG. 25.

FIG. 29 is a diagrammatic sectional view of an array of conductive vias in accordance with an embodiment of the invention and of a substrate fragment in process in accordance with an embodiment of the invention, and corresponds with that of FIG. 23.

DETAILED DESCRIPTION OF EXAMPLE EMBODIMENTS

Example methods of forming a memory array in accordance with some embodiments of the invention are initially described with reference to FIGS. 1-28. FIGS. 1-4 show a small portion of a memory array in fabrication relative to a substrate fragment 10. Control and/or other peripheral circuitry for operating components within the memory array may also be fabricated, and may or may not wholly or partially be within a memory array or sub-array. Further, multiple sub-arrays may also be fabricated and operated independently, in tandem, or otherwise relative one another. As used in this document, a “sub-array” may also be considered as an array. Substrate 10 may be a semiconductor substrate. In the context of this document, the term “semiconductor substrate” or “semiconductive substrate” is defined to mean any construction comprising semiconductive material, including, but not limited to, bulk semiconductive materials such as a semiconductive wafer (either alone or in assemblies comprising other materials thereon), and semiconductive material layers (either alone or in assemblies comprising other materials). The term “substrate” refers to any supporting structure, including, but not limited to, the semiconductive substrates described above.

Substrate 10 comprises base substrate or material 12. Partially or wholly fabricated components of integrated circuitry may be formed as part of, or be elevationally inward of, base substrate 12. Example base substrate 12 comprises bulk semiconductive material 14 having isolation regions 16 formed therein. Semiconductor-on-insulator and other constructions may be used, and whether existing or yet-to-be-developed. Example semiconductive material 14 comprises suitably background doped monocrystalline silicon. Example isolation material 16 comprises doped or undoped silicon dioxide, and/or silicon nitride. Substrate material 14 between isolation regions 16 may be considered as active area 15.

Any of the materials and/or structures described herein may be homogenous or non-homogenous, and regardless may be continuous or discontinuous over any material that such overlie. As used herein, “different composition” only requires those portions of two stated materials that may be directly against one another to be chemically and/or physically different, for example if such materials are not homogenous. If the two stated materials are not directly against one another, “different composition” only requires that those portions of the two stated materials that are closest to one another be chemically and/or physically different if such materials are not homogenous. In this document, a material or structure is “directly against” another when there is at least some physical touching contact of the stated materials or structures relative one another. In contrast, “over”, “on”, and “against” not preceded by “directly”, encompass “directly against” as well as construction where intervening material(s) or structure(s) result(s) in no physical touching contact of the stated materials or structures relative one another. Further, unless otherwise stated, each material may be formed using any suitable existing or yet-to-be-developed technique, with atomic layer deposition, chemical vapor deposition, physical vapor deposition, epitaxial growth, diffusion doping, and ion implanting being examples.

Row line constructions 18 have been formed relative to substrate 12. Example row line constructions 18 comprise conductive (i.e., electrically) material 20 having gate dielectric 22 formed about the base and sidewalls thereof. Example compositions for conductive material 20 are elemental metals, a mixture or alloy of two or more elementals, conductive metal compounds, and conductively-doped semiconductive materials. Example compositions for gate dielectric 22 include silicon dioxide, silicon nitride, high-k dielectrics, ferroelectrics, etc. An example thickness for gate dielectric 22 is about 25 to 70 Angstroms, while an example elevational thickness for conductive material 20 is about 500 to 1,000 Angstroms. In this document, “thickness” by itself (no preceding directional adjective) is the mean straight-line distance through a given material or region perpendicularly from a closest surface of an immediately adjacent material of different composition or of an immediately adjacent region. Additionally, the various materials described herein may be of substantially constant thickness or of variable thicknesses. If of variable thickness, thickness refers to average thickness. In this document, “elevational”, “upper”, “lower”, “top”, and “bottom” are with reference to the vertical direction. “Horizontal” refers to a general direction along a primary surface relative to which the substrate is processed during fabrication, and vertical is a direction generally orthogonal thereto. Further, “vertical” and “horizontal” as used herein are generally perpendicular directions relative one another and independent of orientation of the substrate in three-dimensional space.

Referring to FIGS. 5-8, column line constructions 24 have been formed relative to substrate 12 elevationally outward of row line constructions 18. Column line constructions 24 and row line constructions 18 angle (i.e., other than the straight angle) relative one another. Column line constructions 24 individually comprise a conductive core 26 and dielectric 30 over a top and sidewalls thereof. Example conductive core materials are those described above for conductive material 20. Example dielectric materials 30 are those described above for isolation regions 16.

Row line constructions 18 may be considered and/or function as access lines. Column line constructions 24 may be considered and/or function as sense lines. However, use of “row” and “column” in this document is for convenience in distinguishing one series of lines from another series of lines. Accordingly, “row” and “column” are intended to be synonymous with any series of lines independent of function. Regardless, the rows may be straight and/or curved and/or parallel and/or not parallel relative one another, as may be the columns. Further, the rows and columns may intersect relative one another at 90° or at one or more other angles. In the depicted example, each of the row lines and column lines are shown as being individually straight and angling relative one another at 90°. In one embodiment and as shown, column line constructions 24 are formed to angle perpendicularly (i.e., within 5° of 90° relative to row line constructions 18. In one embodiment and as shown, conductive core material 26 may extend elevationally inward to a respective longitudinal central portion of each active area 15. An example maximum elevational thickness for conductive core material 26 is about 300 to 1,000 Angstroms.

Referring to FIGS. 9-12, conductive lines 32 have been formed elevationally over and angle relative to column line constructions 24. Conductive lines 32 comprise conductive material 33, with examples being those described above for material 20. Conductive lines 32 individually comprise a longitudinally continuous portion 34 and a plurality of conductive material extensions 36 that individually extend elevationally inward between immediately adjacent column line constructions 24 to electrically couple to substrate active area 15.

In one embodiment, conductive lines 32 are formed parallel relative to row line constructions 18. In one embodiment, at least a majority of all conductive material 33 of conductive lines 32 is between immediately adjacent of row line constructions 18 elevationally outward of row line constructions 18. In one embodiment, conductive lines 32 are formed to angle perpendicularly relative to column line constructions 24. In one embodiment, all conductive material 33 of individual conductive lines 32 is formed to be homogenous. In one embodiment, conductive lines 32 are formed to be longitudinally straight linear.

Example conductive lines 32 are shown to be laterally electrically isolated relative one another by dielectric material 37. Example materials are those described above for isolation regions 16. An example technique for forming conductive lines 32 is to first deposit dielectric material 37, and then form trenches therein corresponding to the desired longitudinal outlines of lines 32. Those trenches may then be overfilled with conductive material 33, followed by the polishing of conductive material 33 back at least to the elevationally outermost surfaces of dielectric material 37. Other techniques may be used.

Referring to FIGS. 13-16, mask lines 40 have been formed elevationally over conductive lines 32. Mask lines 40 angle relative to conductive lines 32 and angle relative to column line constructions 24. Mask lines 40 may be straight and/or curved and/or parallel and/or not parallel relative one another. In one embodiment, mask lines 40 are formed to not be perpendicular to either of column line constructions 24 or conductive lines 32. In one embodiment, mask lines 40 are formed to angle relative to row line constructions 18. In one embodiment, mask lines 40 are formed to not be perpendicular to any of column line constructions 24, row line constructions 18, and conductive lines 32. Mask lines 40 may be fabricated of any suitable material. Mask lines 40 may be sacrificial whereby conductive, resistive, or other electrical properties of material of mask lines 40 are not relevant. One example material for mask lines 40 is photoresist. Mask lines 40, including any other structure referred to herein, may be fabricated using pitch multiplication techniques.

In one embodiment, individual mask lines 40 where such cross elevationally over individual conductive lines 32 comprise one longitudinal edge 42 (FIGS. 13 and 15) that is over one of column line constructions 24 and another longitudinal edge 44 opposite edge 42 that is elevationally over one of elevational extensions 36 that is immediately adjacent the one column line construction 24. In one such embodiment, longitudinal edge 42 is elevationally over conductive core material 26 of the one column line construction 24.

Referring to FIGS. 17-20, etching has been conducted elevationally through longitudinally continuous portions 34 of conductive lines 32 (not numerically designated in FIGS. 17-20) and partially elevationally into extensions 36 of conductive lines 32 using mask lines 40 as a mask during such etching to form individual conductive vias 50 to substrate active area 15. In one embodiment and as shown, such act of etching also results in etching into column line constructions 24. In one embodiment and as shown, conductive vias 50 are formed to individually have planar and parallel elevationally outermost and elevationally innermost surfaces 52, 54, respectively, that are laterally displaced yet laterally overlapping relative one another.

Referring to FIGS. 21-24, mask lines 40 (not shown) have been removed.

Referring to FIGS. 25-28, dielectric 37 has been deposited and planarized back at least to elevationally outermost surface of conductive vias 50. Example materials include any of those described above for isolation regions 16. In one embodiment, charge storage devices 58 (FIGS. 26, 27) have been formed elevationally outward and individually electrically coupled to individual of conductive vias 50. Such are diagrammatically and schematically shown, in one example, as being capacitors. In one embodiment, the memory array may comprise DRAM. In one embodiment, the charge storage devices are arrayed in a 2D hexagonal close packed lattice.

Additional embodiments of the invention are next described with reference to FIG. 29 with respect to a substrate fragment 10 a. Like numerals from the above-described embodiments have been used where appropriate, with some construction differences being indicated with the suffix “a” or with different numerals. Conductive vias 50 a have been formed from conductive lines (not shown) comprising an elevationally outer conductive material 33 a (e.g., W) and an elevationally inner conductive material 75 (e.g., TiN) that is of different composition from composition of the elevationally inner conductive material. An example thickness for inner conductive material 75 is about 50 to 250 Angstroms.

In one embodiment, lateral etching is conducted into inner conductive material 75 selectively relative to outer conductive material 33 a to laterally recess inner conductive material 75 from outer conductive material 33 a on at least one side (e.g., the left side in FIG. 29) of individual vias 50 a in at least one straight line vertical cross section (e.g., the cross section shown by FIG. 29). In this document, a selective etch requires removal of one material relative to another stated material at a rate of at least 1.5:1. In one embodiment, elevationally etching is conducted into inner conductive material 75 selectively relative to outer conductive material 33 a to elevationally recess inner conductive material 75 from a curved side surface (e.g., the surface contacted by the arrowhead at the end of a lead-line extending from a numeral 50 a) of outer conductive material 33 a on at least one side of via 50 a (e.g., the right side in FIG. 29) in at least one straight line vertical cross section. By way of example only and where material 33 a is W and material 75 is TiN, W and TiN may be anisotropically etched non-selectively using plasma-based SF₆ and/or CF₄ chemistry to produce an outline of the vias largely corresponding to those shown by vias 50 in FIGS. 17-19. This may be followed by a plasma-based Cl₂ chemistry to isotropically etch TiN selectively relative to W to produce the FIG. 29 construction. Any other attribute(s) or construction(s) as described above may be used.

Embodiments of the invention encompass methods of forming conductive vias independent of whether such are formed in association with memory circuitry. In one such embodiment, at least three spaced (i.e., in at least one vertical straight-line cross section) line constructions (e.g., constructions 24) are formed elevationally over a substrate. The line constructions individually comprise a dielectric top and dielectric sidewalls. A plurality of conductive lines (e.g., lines 32) is formed elevationally over and that angle relative to the line constructions. The conductive lines individually comprise a longitudinally continuous portion and a plurality of conductive material extensions that individually extend elevationally inward between immediately adjacent of the line constructions. Mask lines (e.g., lines 40) are formed elevationally over the conductive lines. The mask lines angle relative to the conductive lines and angle relative to the line constructions. Etching is conducted elevationally through the longitudinally continuous portions and partially elevationally into the extensions using the mask lines as a mask during such etching to form individual conductive vias (e.g., vias 50) extending elevationally between immediately adjacent of the line constructions. Any other attribute(s) or construction(s) as described above may be used.

In one embodiment, a method of forming conductive vias comprises forming at least three spaced line constructions (e.g., constructions 24) elevationally over a substrate. The line constructions individually comprise a dielectric top and dielectric sidewalls. A conductive line (e.g., a line 32) is formed elevationally over and angles relative to the line constructions. The conductive line comprises a longitudinally continuous portion and a plurality of conductive material extensions that individually extend elevationally inward between immediately adjacent of the line constructions. Etching is conducted elevationally through the longitudinally continuous portion and partially elevationally into the extensions at spaced locations (e.g., some locations that are between immediately adjacent mask lines 40 as in FIG. 19) along the conductive line to break-up the longitudinally continuous portion to form individual conductive vias (e.g., vias 50) extending elevationally between immediately adjacent of the line constructions. In one embodiment, an etch mask (e.g., a mask formed by lines 40) that is over the conductive lines between the spaced locations is used during the etching. In one embodiment, the etch mask is formed to comprise spaced masking regions (e.g., the regions of mask lines 40 as in FIG. 19) individually comprising one longitudinal edge that is over one of the line constructions and another longitudinal edge opposite the one edge that is elevationally over one of the extension that is immediately adjacent the one line construction. Any other attribute(s) or construction(s) as described above may be used.

In one embodiment, a method of forming a memory array comprises using one masking step to pattern conductive storage node vias (e.g., conductive storage node vias comprising the elevationally innermost portion of vias 50) and conductive laterally redistributing material (e.g., conductive laterally redistributing material comprising the elevationally outermost portion of vias 50 above line constructions 24, and the masking step and patterning shown by FIGS. 13-20). Any other attribute(s) or construction(s) as described above may be used.

In one embodiment, a method of forming a memory array comprises using a conductive storage node via mask also as a self-aligned conductive laterally redistributing material mask (e.g., the mask shown by lines 40 in FIGS. 13-20 to form conductive storage node vias comprising the elevationally innermost portion of vias 50 and conductive laterally redistributing material comprising the elevationally outermost portion of vias 50 above line constructions 24). In the context of this document, “self-aligned” means a technique whereby at least a lateral surface of a structure is defined by deposition of material against a sidewall of a previously patterned structure. In one such embodiment, the storage node via and redistributing material mask is self-aligned along one direction that is between immediately adjacent conductive line constructions and between which is the redistributing material and material of the vias (e.g., conductive material 33 is self-aligned to and by sidewall material 30 between immediately adjacent line constructions 24 along a direction such as line 19-19 in FIG. 17). Any other attribute(s) or construction(s) as described above may be used.

Embodiments of the invention include an array of conductive vias independent of method of manufacture, and for example as shown in FIG. 29. In one embodiment, an array of conductive vias comprises spaced line constructions (e.g., constructions 24) individually comprising a dielectric top and dielectric sidewalls. Individual conductive vias (e.g., vias 50 a) extend elevationally between immediately adjacent of the line constructions. The individual vias comprise an elevationally inner conductive material (e.g., material 75) and an elevationally outer conductive material (e.g., material 33 a) of different composition from composition of the elevationally inner conductive material. The elevationally inner conductive material is laterally recessed from the elevationally outer conductive material on at least one side of the individual via in at least one straight line vertical cross section. Other attribute(s) or construction(s) as described above may be used.

In one embodiment, an array of conductive vias comprises spaced line constructions (e.g., constructions 24) individually comprising a dielectric top and dielectric sidewalls. Individual conductive vias (e.g., vias 50 a) extend elevationally between immediately adjacent of the line constructions. The individual vias comprise an elevationally inner conductive material (e.g., material 75) and an elevationally outer conductive material (e.g., material 33 a) of different composition from composition of the elevationally inner conductive material. The elevationally inner conductive material is elevationally recessed from a curved side surface of the elevationally outer conductive material on at least one side of the individual via in at least one straight line vertical cross section. Other attribute(s) or construction(s) as described above may be used.

CONCLUSION

In some embodiments, a method of forming a memory array comprises forming row line constructions and column line constructions relative to a substrate, the row line constructions and the column line constructions angling relative one another. The column line constructions are elevationally outward of the row line constructions. The column line constructions individually comprise a conductive core and dielectric over a top and over sidewalls of the conductive core. Conductive lines are formed elevationally over and that angle relative to the column line constructions. The conductive lines individually comprise a longitudinally continuous portion and a plurality of conductive material extensions that individually extend elevationally inward between immediately adjacent of the column line constructions to electrically couple to substrate active area. Mask lines are formed elevationally over the conductive lines. The mask lines angle relative to the conductive lines and angle relative to the column line constructions. Etching is conducted elevationally through the longitudinally continuous portions and partially elevationally into the extensions using the mask lines as a mask during said etching to form individual conductive vias that electrically couple to the substrate active area.

In some embodiments, a method of forming conductive vias comprises forming at least three spaced line constructions elevationally over a substrate. The line constructions individually comprise a dielectric top and dielectric sidewalls. A plurality of conductive lines is formed elevationally over and that angle relative to the line constructions. The conductive lines individually comprise a longitudinally continuous portion and a plurality of conductive material extensions that individually extend elevationally inward between immediately adjacent of the line constructions. Mask lines are formed elevationally over the conductive lines. The mask lines angle relative to the conductive lines and angle relative to the line constructions. Etching is conducted elevationally through the longitudinally continuous portions and partially elevationally into the extensions using the mask lines as a mask during said etching to form individual conductive vias extending elevationally between immediately adjacent of the line constructions.

In some embodiments, a method of forming conductive vias comprises forming at least three spaced line constructions elevationally over a substrate. The line constructions individually comprise a dielectric top and dielectric sidewalls. A conductive line is formed elevationally over and angles relative to the line constructions. The conductive line comprises a longitudinally continuous portion and a plurality of conductive material extensions that individually extend elevationally inward between immediately adjacent of the line constructions. Etching is conducted elevationally through the longitudinally continuous portion and partially elevationally into the extensions at spaced locations along the conductive line to break-up the longitudinally continuous portion to form individual conductive vias extending elevationally between immediately adjacent of the line constructions.

In some embodiments, a method of forming a memory array comprises using one masking step to pattern conductive storage node vias and conductive laterally redistributing material.

In some embodiments, a method of forming a memory array comprises using a conductive storage node via mask also as a self-aligned conductive laterally redistributing material mask.

In some embodiments, an array of conductive vias comprises spaced line constructions individually comprising a dielectric top and dielectric sidewalls. Individual conductive vias extend elevationally between immediately adjacent of the line constructions. The individual vias comprise an elevationally inner conductive material and an elevationally outer conductive material of different composition from composition of the elevationally inner conductive material. The elevationally inner conductive material is laterally recessed from the elevationally outer conductive material on at least one side of the individual via in at least one straight line vertical cross section.

In some embodiments, an array of conductive vias comprises spaced line constructions individually comprising a dielectric top and dielectric sidewalls. Individual conductive vias extend elevationally between immediately adjacent of the line constructions. The individual vias comprise an elevationally inner conductive material and an elevationally outer conductive material of different composition from composition of the elevationally inner conductive material. The elevationally inner conductive material is elevationally recessed from a curved side surface of the elevationally outer conductive material on at least one side of the individual via in at least one straight line vertical cross section.

In compliance with the statute, the subject matter disclosed herein has been described in language more or less specific as to structural and methodical features. It is to be understood, however, that the claims are not limited to the specific features shown and described, since the means herein disclosed comprise example embodiments. The claims are thus to be afforded full scope as literally worded, and to be appropriately interpreted in accordance with the doctrine of equivalents. 

The invention claimed is:
 1. An array of conductive vias, comprising: spaced line constructions individually comprising a dielectric top and dielectric sidewalls; and conductive vias extending elevationally between immediately adjacent of the line constructions, the conductive vias individually comprising an elevationally inner conductive material and an elevationally outer conductive material of different composition from composition of the elevationally inner conductive material, the elevationally inner conductive material being laterally recessed from the elevationally outer conductive material on at least one side of an individual conductive via of the conductive vias in at least one straight line vertical cross section.
 2. The array of claim 1 wherein the elevationally inner conductive material is laterally recessed from the elevationally outer conductive material on only one side of the individual conductive via in the at least one straight line vertical cross section, the elevationally inner conductive material being elevationally recessed from a curved side surface of the elevationally outer conductive material on a side of the individual conductive via opposite the only one side in the at least one straight line vertical cross section.
 3. The array of claim 1 wherein the spaced line constructions comprise column line constructions of memory circuitry and further comprising row line constructions of memory circuitry that intersect at an angle relative to the column line construction, the column line constructions being elevationally outward of the row line constructions, the column line constructions individually comprising a conductive core.
 4. The array of claim 3 wherein the elevationally inner conductive material is laterally recessed from the elevationally outer conductive material on only one side of the individual conductive via in the at least one straight line vertical cross section, the elevationally inner conductive material being elevationally recessed from a curved side surface of the elevationally outer conductive material on a side of the individual conductive via opposite the only one side in the at least one straight line vertical cross section.
 5. An array of conductive vias, comprising: spaced line constructions individually comprising a dielectric top and dielectric sidewalls; and conductive vias extending elevationally between immediately adjacent of the line constructions, the conductive vias individually comprising an elevationally inner conductive material and an elevationally outer conductive material of different composition from composition of the elevationally inner conductive material, the elevationally inner conductive material being elevationally recessed from a curved side surface of the elevationally outer conductive material on at least one side of an individual conductive via of the conductive vias in at least one straight line vertical cross section.
 6. The array of claim 1 wherein the conductive vias individually have planar and parallel elevationally outermost and elevationally innermost surfaces that are laterally displaced yet laterally overlapping relative to one another.
 7. The array of claim 5 wherein the conductive vias individually have planar and parallel elevationally outermost and elevationally innermost surfaces that are laterally displaced yet laterally overlapping relative to one another.
 8. The array of claim 1 wherein the conductive vias individually have planar elevationally outermost surfaces of a parallelogram shape in 2D horizontal cross section.
 9. The array of claim 5 wherein the conductive vias individually have planar elevationally outermost surfaces of a parallelogram shape in 2D horizontal cross section.
 10. A memory array, comprising: a substrate comprising active area, row line constructions, and column line constructions; the row line constructions and the column line constructions intersect at an angle relative to one another, the column line constructions being elevationally outward of the row line constructions, the column line constructions individually comprising a conductive core and dielectric over a top and over sidewalls of the conductive core; conductive vias extending elevationally between immediately adjacent of the column line constructions and electrically coupling to substrate active area, the conductive vias individually comprising an elevationally inner conductive material and an elevationally outer conductive material of different composition from composition of the elevationally inner conductive material, the elevationally inner conductive material being laterally recessed from the elevationally outer conductive material on at least one side of an individual conductive via of the conductive vias in at least one straight line vertical cross section; and charge storage devices elevationally outward and individually electrically coupled to individual of the conductive vias.
 11. The memory array of claim 10 wherein the charge storage devices are arrayed in a 2D hexagonal close packed lattice.
 12. The array of claim 10 wherein the conductive vias individually have planar and parallel elevationally outermost and elevationally innermost surfaces that are laterally displaced yet laterally overlapping relative to one another.
 13. The array of claim 10 wherein the conductive vias individually have planar elevationally outermost surfaces of a parallelogram shape in 2D horizontal cross section.
 14. A memory array, comprising: a substrate comprising active area, row line constructions, and column line constructions; the row line constructions and the column line constructions intersect at an angle relative to one another, the column line constructions being elevationally outward of the row line constructions, the column line constructions individually comprising a conductive core and dielectric over a top and over sidewalls of the conductive core; conductive vias extending elevationally between immediately adjacent of the column line constructions and electrically coupling to substrate active area, the conductive vias individually comprising an elevationally inner conductive material and an elevationally outer conductive material of different composition from composition of the elevationally inner conductive material, the elevationally inner conductive material being elevationally recessed from a curved side surface of the elevationally outer conductive material on at least one side of an individual conductive via of the conductive vias in at least one straight line vertical cross section; and charge storage devices elevationally outward and individually electrically coupled to individual of the conductive vias.
 15. The memory array of claim 14 wherein the charge storage devices are arrayed in a 2D hexagonal close packed lattice.
 16. The array of claim 14 wherein the conductive vias individually have planar and parallel elevationally outermost and elevationally innermost surfaces that are laterally displaced yet laterally overlapping relative to one another.
 17. The array of claim 14 wherein the conductive vias individually have planar elevationally outermost surfaces of a parallelogram shape in 2D horizontal cross section. 